Model M Manual : Appendix
Carbon Dioxide Information (CO2)
Carbon dioxide is a nonflammable, colorless, odorless, slightly acid
gas. It is one and one-half times as heavy as air. CO2 is used in the
carbonation of soda pop, as an inert agent in fire extinguishers, in
canned food products, and many other applications.
Below 88°F, confined CO2 liquid and gas are in equilibrium at a vapor
pressure shown in the table below. For example, a container of CO2 liquid
and gas at 59°F has a pressure of 723-psia. As gas is removed from the
cylinder, the liquid vaporizes into a gas, which maintains the vapor
pressure shown. When all of the liquid has been vaporized, the gas
pressure will reduce as gas is withdrawn. Following is a table of the
vapor pressure as a function of temperature.
| Temperature |
|
Pressure |
| °F |
°C |
|
PSI |
Bar |
| 88 |
31 |
|
1053 |
73 |
| 59 |
15 |
|
723 |
50 |
| 32 |
0 |
|
490 |
34 |
| 5 |
-15 |
|
317 |
22 |
| -22 |
-30 |
|
192 |
13 |
Above 88°F, CO2 becomes a fluid. Liquid does not exist separate from
gas. The pressure in the tank is an indication of the amount of CO2
present in the tank. As the gas is used, the pressure will decline. At
90°F, the pressure in a full cylinder will be approximately 1100-psi.
The amount of CO2 in a cylinder is determined by weighing the cylinder
containing the CO2 and then subtracting the weight of the empty cylinder
which is shown on the cylinder. Below 88°F, the amount of CO2 in the
cylinder cannot be estimated by measuring the pressure unless the pressure
is less than the vapor pressure shown on the graph. If the pressure is
less than the vapor pressure, the container does not contain any liquid
CO2 and very little CO2 remains in the container.
CO2 is heavier than air and may collect in confined, unventilated
areas. Do not permit a leaking cylinder in a closed automobile. CO2 is the
regulator of the breathing function, and an increase in the CO2 inhaled
will cause an increased rate of breathing. In high concentrations, CO2 can
paralyze the respiratory system. Do not breathe air having excessive
amounts of CO2.
Do not overfill a CO2 container or dangerous pressures can result. Do
not use CO2 cylinders, which show any sign of wear, abuse, corrosion, worn
threads or any mishandling.
| PHYSICAL CONSTANTS |
| Density, Gas @ 70°F, 1atm |
0.1146 lb/cu ft |
| Critical Temperature |
87.8°F (31°C) |
| Critical Density |
0.468 g/ml |
| Critical Pressure |
1072-psia (73-atm) |
| Specific Gravity |
1.53 |
| Specific Volume @ 70°F, 1-atm |
8.76 cu ft/lb
or 15,000 cu in/lb
or 950 cu in/oz |